Table 3. Enantioselective Sulfenylation of Various Silyl Enol Ethers.


Yield of isolated, analytically pure product. All reactions were carried out on a 1.0 mmol scale.
The enantiomeric ratio was determined by CSP-SFC analysis or CSP-HPLC analysis, as required.
10 mol % Lewis base was used in this instance.
% conversion determined by GC analysis using biphenyl as an internal standard.
After one recrystallization from MeOH.