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. 2014 Aug 19;136(37):13029–13037. doi: 10.1021/ja506611k

Table 3. Effect of Concentration and Equivalents of Terminal Olefin on the AROCM of Norbornene 9c.

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concentration (M) equiv 10a conversion (%)a Z/E ratiob Z ee (%)c
0.1 7 >95 44:56 96
0.5 7 >95 70:30 95
0.5 3 >95 59:41 96
a

Determined by 500 MHz 1H NMR.

b

Determined by GC.

c

Determined by chiral SFC on chromatographically purified products