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. 2014 Sep 18;136(39):13506–13509. doi: 10.1021/ja506532h

Table 2. Cyclic Sulfamide Formation with Selected Alkenes.

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a

Reactions were performed in i-PrOAc with 1 equiv of substrate, 2 mol % Rh2(esp)2, 1.1 equiv of BocNHSO2NH2, 1.1 equiv of PhI(OAc)2, and 2.3 equiv of MgO. After the completion of the aziridination reaction, 1.1 equiv of NaI and DMF were added to induce rearrangement.

b

Isolated yields following chromatographic purification.

c

Product isolated as a single diastereomer.

d

dr = 1:1.

e

See ref (14).

f

Reaction performed with 10 equiv of substrate.