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Correlation between gas-phase ionization energies for MII/MIII and MII/MIII redox processes of (a) (DPP)M, (b) (OETPP)M, and (c) (TPP)M in PhCN containing 0.1 M TBAP (see Table 1 for potential). The ionization energies are taken from ref (42). The CuII/CuIII process of (TPP)Cu is predicted to occur at 2.47 V based on the correlation in part c.
