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. 2014 Sep 25;53(19):10772–10778. doi: 10.1021/ic502162p

Table 2. Absorption Maxima (λmax, nm) of Nickel Tetraalkylporphyrins and Their Singly Oxidized Products in PhCN and Py Containing 0.1 M TBAP.

  in PhCN
in Py
  (TRP)NiII
[(TRP)NiII]+
(TRP)NiII
[(TRP)NiIII (Py)2]+
compound Soret visible Soret vsible Soret visible Soret visible
1 455 584, 622 422 778 452 583, 625 469 596, 646
2 426 550, 583 413 689 424 548, 589 445 571, 608
3 424 545, 583 415 700 424 545, 584 443 563, 600
4 421 539, 582 411 688 421 542, 582 441 560, 601