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. Author manuscript; available in PMC: 2015 Oct 1.

Published in final edited form as: Chem Sci. 2014 Jul 3;5(10):4091–4098. doi: 10.1039/C4SC01541J

Table 2.

Homodimerization of allyl benzene (29).


catalyst	time (h)	conversion (%)^a	Z-selectivity (%)^a	30/31 ^a

	1	93	92	>50
	3	98	84	>50
	7	>99	66	>50
	12	>99	45	>50

	1	92	>95	>50
	3	98	>95	>50
	7	>99	91	>50
	12	>99	83	>50

	1	0	n/a	n/a
	3	0	n/a	n/a
	7	0	n/a	n/a
	12	0	n/a	n/a

	1	72	>95	>50
	3	92	95	>50
	7	97	72	>50
	12	99	53	>50

	1	82	>95	>50
	3	94	95	>50
	7	97	90	>50
	12	99	79	>50

	1	75	>95	>50
	3	91	>95	>50
	7	97	>95	>50
	12	98	92	>50

	1	84	97	>50
	3	95	90	>50
	7	>99	54	>50
	12	>99	25	>50

	1	13	>95	>50
	3	75	>95	>50
	7	95	>95	>50
	12	98	93	>50
	25	>99	74	>50

	1	4	50	17
	3	6	49	2
	7	10	49	1
	12	15	49	0.6

^a

Determined from analysis of the ¹H NMR spectrum.