. Author manuscript; available in PMC: 2015 Jun 2.

Published in final edited form as: Chemistry. 2014 Apr 29;20(23):6857–6860. doi: 10.1002/chem.201402289

Table 1.

Rate constants for the reaction with peroxyl radicals (k_ROO) in PhCN, at 30 °C, and number of radicals trapped by each phenolic moiety (n) determined from styrene autoxidation studies.

	k_ROO [10⁴ m⁻¹ s⁻¹]	n
CoNPs	<0.1	–
CoNPs–N₃	<0.1	–
CoNPs–Oct	<0.1	–
CoNPs–TOH	560±150^[a]	1.1±0.1^[a]
TOH	64±10	2.2±0.2

^[a]

Data referred to the first inhibition period, see text.