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. 2014 Sep 24;57(20):8622–8634. doi: 10.1021/jm501259v

Table 1. Absorption Maxima (λmax) and Molar Extinction Coefficients (ε) in CH3OH, Fluorescence Emission Maxima (λFL) and Quantum Yields for Fluorescence (ΦFL) in CH3OH, Quantum Yields for the Generation of Singlet Oxygen [Φ(1O2)] in CH3OH, n-Octanol/Water Partition Coefficients (log P) for Thiorhodamines 15a18a and Selenorhodamines 15b18ba.

compd λmax, nm ε, M–1 cm–1 λFL, nm ΦFL Φ(1O2) log P
15ab 597 6.77 × 104 626 0.09 ± 0.01 <0.05 1.4
15b 609 7.18 × 104 636 0.009 ± 0.001 0.50 ± 0.03 2.26 ± 0.04
16ab 597 6.30 × 104 626 0.07 ± 0.01 <0.05 2.7
16b 608 9.78 × 104 635 0.008 ± 0.001 0.54 ± 0.03 2.41 ± 0.04
17ab 598 8.31 × 104 626 0.09 ± 0.01 <0.05 1.7
17b 609 8.73 × 104 634 0.009 ± 0.001 0.48 ± 0.03 2.23 ± 0.04
18ab 598 6.18 × 104 626 0.07 ± 0.01 <0.05 2.6
18b 608 8.11 × 104 634 0.008 ± 0.001 0.44 ± 0.03 1.61 ± 0.06
a

Error limits are ±SD.

b

Values of λmax, ε, and log P for 15a18a are taken from ref (28).