Table 1. Absorption Maxima (λmax) and Molar Extinction Coefficients (ε) in CH3OH, Fluorescence Emission Maxima (λFL) and Quantum Yields for Fluorescence (ΦFL) in CH3OH, Quantum Yields for the Generation of Singlet Oxygen [Φ(1O2)] in CH3OH, n-Octanol/Water Partition Coefficients (log P) for Thiorhodamines 15a–18a and Selenorhodamines 15b–18ba.
compd | λmax, nm | ε, M–1 cm–1 | λFL, nm | ΦFL | Φ(1O2) | log P |
---|---|---|---|---|---|---|
15ab | 597 | 6.77 × 104 | 626 | 0.09 ± 0.01 | <0.05 | 1.4 |
15b | 609 | 7.18 × 104 | 636 | 0.009 ± 0.001 | 0.50 ± 0.03 | 2.26 ± 0.04 |
16ab | 597 | 6.30 × 104 | 626 | 0.07 ± 0.01 | <0.05 | 2.7 |
16b | 608 | 9.78 × 104 | 635 | 0.008 ± 0.001 | 0.54 ± 0.03 | 2.41 ± 0.04 |
17ab | 598 | 8.31 × 104 | 626 | 0.09 ± 0.01 | <0.05 | 1.7 |
17b | 609 | 8.73 × 104 | 634 | 0.009 ± 0.001 | 0.48 ± 0.03 | 2.23 ± 0.04 |
18ab | 598 | 6.18 × 104 | 626 | 0.07 ± 0.01 | <0.05 | 2.6 |
18b | 608 | 8.11 × 104 | 634 | 0.008 ± 0.001 | 0.44 ± 0.03 | 1.61 ± 0.06 |
Error limits are ±SD.
Values of λmax, ε, and log P for 15a–18a are taken from ref (28).