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. 2014 Aug 20;136(41):14345–14348. doi: 10.1021/ja506229s

Table 2. Borylations with 5/[Ir(OMe)(cod)]2 Catalysta.

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a

Typically reactions were run on 1 mmol scale with equimolar B2pin2 and substrate with 2.5 mol % 5 and 1.25 mol % [Ir(OMe)(cod)]2. Unless noted, yields are for isolated materials. See SI for details.

b

Reaction solvent was THF.

c

2.0 equiv B2pin2 was used.

d

GC-conversion with a 6:1:2 ratio of o:m + p:diborylated products.

e

Reaction solvent was n-hexane.

f

Approximately 15% of the crude mixture was the diorthoborylated compound (8j′ in the SI).