Table 8. Yields of H2 by Treatment of Various Catalysts (4.2 mM FeFe Complex in CH2Cl2) with [H(OEt2)2]BArF4.
FeFe complex | amt of H+, equiv | amt of Fc*, equiv | amt of H2, equiv | time,a h |
---|---|---|---|---|
1 | 10 | 5 | 3.3 ± 0.3 | 0.5 |
2 | 10 | 5 | 3.3 ± 0.3 | 2.0 |
3 | 10 | 5 | 2.7 ± 0.5 | 1.5 |
4 | 10 | 5 | 0.04 ± 0.01 | 0.5 |
Approximate period for maximum yield of H2.