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. Author manuscript; available in PMC: 2014 Oct 28.
Published in final edited form as: J Phys Chem B. 2013 May 17;117(21):6512–6523. doi: 10.1021/jp401243m

TABLE II.

Decomposition of ΔH(z) into water-water and ion-water components at some significant z-positions. Refer to text for the detail definition. The units are in kcal/mol.

System ΔHww ΔHiw ΔHww
I
280 K −13.97 11.35 37.17
300 K −10.62 10.18 34.90
320 K −10.31 8.83 32.50
340 K −8.04 7.42 29.58
360 K −7.38 7.84 27.11
Cl
280 K −8.85 11.22 31.92
300 K −5.61 8.11 30.02
320 K −4.78 6.97 27.53
340 K −4.08 4.10 25.38
360 K −3.06 3.20 23.16