Table 2. Reactivity Ratios of the Three Monomers Used in the Statistical Copolymers, Determined by Altering the Feed Ratio (f1) of Each Monomer and Polymerizing Using a Free-Radical Approach at 70 °C in 500 MHz Variable Temperature NMRa.
r2 |
|||
---|---|---|---|
r1 | MAG | AEMA | DMAEMA |
MAG | 1.54 | 0.88 | |
AEMA | 0.30 | 0.63 | |
DMAEMA | 0.19 | 0.61 |
The r1 and r2 values were calculated from eq 1. r1 = (k11/k12), and r2 = (k22/k21).