Table 5.

Chemoselective Suzuki-Miyaura cross-coupling of 2-B(pin)-substituted allylic acetates with aryl iodides.

Entry	Acetate	Ar-I	Product		Yield (%)[a]
1	1a	Ph-I		6a	96
2	1a	4-MeO-C6H4-I		6b	60
3	1a	4-O2N-C6H4-I		6c	92
4	1b	Ph-I		6d	67
5	1d	Ph-I		6e	99
6	1d	4-O2N-C6H4-I		6f	92
7	1f	Ph-I		6g	70[b]
8	1f	4-O2N-C6H4-I		6h	75[b]

^[a]Yield of isolated and purified products.

^[b]The reaction was conducted at 75°C in THF/H₂O (10:1).