Table 6.

Chemoselective Suzuki-Miyaura cross-coupling of 2-B(pin)-substituted allylic acetates with aryl bromides.

Entry	Acetate	Ar-Br	Product		Yield (%)[a]
1	1a	Ph-Br		6a	73
2	1a	4-MeO-C6H4-Br		6b	54
3	1a	4-O2N-C6H4-Br		6c	91
4	1a	4-F3C-C6H4-Br		6j	85
5	1a	2-MeO-C6H4-Br		6k	80
6	1b	Ph-Br		6d	87
7	1d	4-O2N-C6H4-Br		6f	90
8	1f	4-O2N-C6H4-Br		6h	80[b]
9	1a			6l	74
10	1a			6m	82

^[a]Yield of isolated and purified products.

^[b]The reaction was conducted at 75 °C in THF/H₂O (10:1).