Table 7.

Chemoselective Suzuki-Miyaura cross-coupling of 2-B(pin)-substituted allyl benzoates and carbonates

Entry	2-B(pin)-substituted allyls		Ar-X	Product		Yield (%)[a]
1		7a	Ph-I		9a	96
2		7a	Ph-Br		9a	38
3		7a	4-CF3-C6H4-Br		9b	76
4		8a	Ph-I		9c	91
5		8a	4-NO2-C6H4-I		9d	78
6		8a	4-NO2-C6H4-Br		9d	75
7		8a	4-CF3-C6H4-Br		9e	57
8		8b	Ph-I		9f	83
9		7b	Ph-I			–[b]
10		8c	Ph-I			–[b]

^[a]Yield of isolated and purified products.

^[b]Starting materials were decomposed.