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a) Photoregeneration of 1,4-NADH using water as an electron donor: after 6 hours of irradiation of the NAD+/water solutions in the presence of various photocatalysts. b) Photoregeneration of 1,4-NADH using several photocatalysts, and [Cp*Rh(bpy)H2O]Cl2 as an electron mediator or an H−-transfer agent. Note that the addition of glycerol to water improves the conversion yield and accelerate the reaction (see below).
