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. 2014 Oct 28;10:2513–2520. doi: 10.3762/bjoc.10.262

Table 4.

The epoxide ring opening reactions of 6a,b.

graphic file with name Beilstein_J_Org_Chem-10-2513-i004.jpg

Entry Epoxide Nu Catalyst Product Yield (%)a

1 6a 7d Cs2CO3 13a 68b
2 6b 7d Cs2CO3 13b 55b
3 6a 7a Zn(ClO4)2·6H2O 14a 84c
4 6b 7a Zn(ClO4)2·6H2O 14b 80c
15 6d

aIsolated yield. bReagents and conditions: 5.0 mmol epoxide, 10.0 mol % catalyst, 6.5 mmol nucleophile, DMSO (10 mL), 120 °C, 2 h. cReagents and conditions: 5.0 mmol epoxide, 10.0 mol % catalyst, 6.5 mmol nucleophile, neat, 100 °C, 2 h. dRegioisomeric ratio (14b:15) – 12:1.