Table 5. Scope of the Nucleophilic Compatibility.


1 equiv of 1a, 1.2 equiv of NaN3, dry CH3CN (0.1 M), 76 °C, 2 h.
1 equiv of 1a, 1.5 equiv of NaSCN, dry CH3CN (0.1 M), 76 °C, 1 h.
1 equiv of 1a, 1.2 equiv of potassium phthalimide, 10 mol % of 18-crown-6, dry toluene (0.2 M), 100 °C, 1 h.
1 equiv of 1a, 1 equiv of Na2CO3, DMF/CH3CN/H2O (0.15 M), 25 °C, 12 h.
1 equiv of 1a, 1.01 equiv of 1-methylimidazole, dry THF (0.2 M), 25 °C, 12 h.