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. 2014 Mar 11;53(15):3941–3946. doi: 10.1002/anie.201311161

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© 2014 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.

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Reactions of 1-Cl and 1-py with NADH. a) ¹H NMR spectra of the reaction between 1-Cl (0.25 mm) and NADH (3.5 mol equiv) in CD₃OD/H₂O (1:1) at 310 K. Left: low-field region; right: high-field region showing the resonances that arise from the Cp methyl substituents; top: Ir–H hydride peak (×4). b) UV/Vis spectra of the reaction of NADH (87 μm) with 1-Cl (0.8 μm) in MeOH/H₂O (1.6:98.4) at 310 K for 20 h. c) Detection of hydrogen peroxide in a solution of 1-py (1 mm) with NADH (3 mol equiv) in MeOH/H₂O (3:7, v/v) at 310 K. After 24 hours, H₂O₂ (ca. 0.22 mm) was detected by Quantofix peroxide test sticks.