. 2014 Jun 3;136(24):8568–8576. doi: 10.1021/ja504886x

Table 3. Arylation with Aryl Halides^a.

2.3.

Conditions: arene (0.25 mmol), ArX (0.375–0.75 mmol), TMPLi (1–1.25 mmol), Et₂O/THF, pentane/THF, THF, or Et₂O solvent, −65 to −15 °C. Yields are isolated yields. See Supporting Information for details.

Heterocycle (1 mmol), PhCl (0.5 mmol), TMPLi (1.8 mmol), cyclohexane/Et₂O solvent, 23 °C.

Table 3. Arylation with Aryl Halidesa.

Table 3. Arylation with Aryl Halides^a.