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. Author manuscript; available in PMC: 2014 Nov 12.
Published in final edited form as: J Am Soc Mass Spectrom. 2011 Jul 6;23(4):577–593. doi: 10.1007/s13361-011-0190-0

Scheme 2.

Scheme 2

Structures and CID-MS/MS fragmentation reactions of the stable isotope labeled DMBNHS reagents S,S′-dimethylthio-d6-butanoylhydroxysuccinimide ester iodide (D6-light DMBNHS) and S,S′-d6-dimethylthiobutanoylhydroxysuccinimide ester iodide (D6-heavy DMBNHS)