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. 2014 Nov 12;9(11):e113142. doi: 10.1371/journal.pone.0113142

Table 2. Relative abundances (%) of di- and triterpenoids identified in commercial specimens of Boswellia resins.

Compound classes CommonName SystematicName Type Boswellia carterii Boswellia sacra Boswellia serrata Boswellia papyrifera
Diterpenoids cembrene A C 1.0 2.1 1.7 1.8
cembrene isomer (?) C 0.2 1.4 0.8 -
serratol isomer (?) C 0.2 1.8 0.9 -
cembrene C C 0.3 1.7 0.5 0.2
verticilla-4(20),7,11-triene - - - 6.6
unknown (?) 2.3 1.0 0.7 0.2
incensol C 17.7 tr tr 6.9
serratol C 7.0 13.7 14.3 -
incensol acetate C - - - 11.8
incensol oxide acetate C - - - 0.1
Triterpenoids epi-β-amyrin olean-12-en-3α-ol O 3.6 2.9 0.9 0.1
epi-α-amyrin urs-12-en-3α-ol U 10.2 5.0 3.0 0.3
epi-lupeol lup-20(29)-en-3α-ol L 3.8 4.5 0.7 0.3
tirucallol tirucalla-8,24-dien-3-ol T 0.2 0.4 0.6 0.4
β-amyrenone olean-12-en-3-one O 0.5 3.8 0.5 ce
β-amyrin olean-12-en-3β-ol O ce ce ce ce
α-amyrenone urs-12-en-3-one U 1.0 10.8 1.1 0.5
α-amyrin urs-12-en-3β-ol U 2.6 3.0 1.8 0.6
lupeol lup-20(29)-en-3β-ol L 0.4 1.0 ce ce
α-boswellic acid 3α-hydroxy-olean-12-en-24-oic acid O 7.6 4.6 9.3 4.8
β-boswellic acid 3α-hydroxy-urs-12-en-24-oic acid U 13.5 14.8 23.2 11.3
lupeolic acid 3α-hydroxy-lup-20(29)-en-24-oicacid L 1.1 1.5 0.3 0.1
11-hydroxy-β-boswellic acid 3α,11α-dihydroxy-urs-12-en-24-oicacid U 0.7 - 0.4 0.9
β-elemonic acid 3-oxo-tirucalla-8,24-dien-21-oicacid T 2.9 tr 6.0 13.9
β-elemolic acid 3-hydroxy-tirucalla-8,24-dien-21-oicacid T 1.5 tr 0.3 2.2
3-O-acetyl-β-elemolic acid 3-acetoxy-tirucalla-8,24-dien-21-oicacid T 0.4 tr 5.9 5.5
3-O-acetyl-α-boswellic acid 3α-acetoxy-olean-12-en-24-oic acid O 3.9 6.3 5.5 7.1
3-O-acetyl-β-boswellic acid 3α-acetoxy-urs-12-en-24-oic acid U 9.3 14.5 18.3 11.2
3-O-acetyl-lupeolic acid 3α-acetoxy-lup-20(29)-en-24-oicacid L 1.0 2.1 0.1 0.5
3-O-acetyl-11-hydroxy-β-boswellic acid 3α-acetoxy-11α-hydroxy-urs-12-en-24-oic acid U 0.6 tr 0.2 2.2
11-keto-β-boswellic acid 3α-hydroxy-11-oxo-urs-12-en-24-oicacid U 0.8 0.4 1.5 2.0
3-O-acetyl-11-keto-β-boswellic acid 3α-acetoxy-11-oxo-urs-12-en-24-oicacid U 5.6 2.7 1.6 8.3
Total amyrins: epi -amyrins (3α-OH), amyrenones (3-oxo) and amyrins (3β-OH) 17.9 25.4 7.3 1.5
Total boswellic acids: boswellic acids, hydroxy/keto boswellic acids and their acetates 42.0 43.3 60.0 47.8
Total lupanes (L): epi-lupeol, lupeol, lupeolic acid and its acetate 6.3 9.1 1.1 0.9
Total tirucallanes (T): β-elemonic acid, β- elemolic acid and its acetate 5.0 0.4 12.7 22.1
Ratio of ursanes (U) to oleananes (O) a 2.2 2.5 2.8 1.9
Ratio of 3- O -acetyl-11-keto-β-boswellic acid to 11-keto-β-boswellic acid 6.9 6.4 1.1 4.2

Legend: - = not detected, ce = co-eluting compound which could not be resolved with mass spectral deconvolution, tr = trace, italic numbers are deconvoluted compounds. Structure types: C = cembrane, O = oleanane, U = ursane, L = lupane, T = tirucallane. Major diterpenoid and triterpenoid structures are depicted in figure S1.

a

Calculated using epi-amyrins, boswellic acids and 3-O-acetyl-boswellic acids.