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General reaction scheme for synthesis of the I45DC analogs. Conditions: a) SOCl2, cat. DMF, Toluene, 85 °C; b) DIPEA, substituted aniline, DCM, −10 °C; c) acetonitrile:water (1:1), K2CO3, PdCl2TPP2, boronic acid; d) DIPEA, substituted aniline or benzyl amine, DCM, room temperature (rt).
