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. Author manuscript; available in PMC: 2015 Dec 28.
Published in final edited form as: Dalton Trans. 2014 Oct 14;43(48):17949–17963. doi: 10.1039/c4dt02483d

Figure 4.

Figure 4

Left: 5 K perpendicular-mode EPR spectrum of the conversion of [MnII(TpPh2)(DMF)3](OTf) to [MnIII(O2)(TpPh2)(THF)] and purification of [MnIII(O2)(TpPh2)(THF)]. Right: 5 K parallel-mode EPR spectrum of [MnIII(O2)(TpPh2)(THF)] (red) and simulation (green) with D = −2.0(5), E/D = 0.07(1). Inset: signal intensity versus temperature of g = 8.3 signal. An EPR spectrum of [MnIII(O2)(TpPh2)(THF)] showing a wider field is in ESI, Figure S3.