. Author manuscript; available in PMC: 2015 Dec 28.

Published in final edited form as: Dalton Trans. 2014 Oct 14;43(48):17949–17963. doi: 10.1039/c4dt02483d

Table 3.

Mn-N_pyrazole bond lengths (Å) for [Mn^II(Tp^Ph2)(DMF)₃](OTf) and other Mn^II(Tp) complexes.

	Mn-N(1)	Mn-N(2)	Mn-N(3)	Ref
[Mn^II(Tp^Ph2)(DMF)₃](OTf)	2.286(1)	2.250(3)	2.319(1)	This work
[Mn(Tp^CO2Et,Me)(H₂O)₃]ClO₄	2.254(4)	2.273(4)	2.307(4)	⁵⁶
[Mn(OAc)(Tp^Ph,Me)(pz^Ph,MeH)]	2.199(2)	2.282(2)	2.149(2)	⁵⁷
[Mn(Cl)(Tpⁱ^Pr2)(pzⁱ^Pr2H)]	2.151(2)	2.164(2)	2.243(2)	⁵⁷