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Selected bond lengths (Å) and angles (°) for [MnIII(O2)(TpPh2)(THF)].
| Mn-O(1) | 1.865(2) | O(1)-O(2) | 1.432(3) |
| Mn-O(2) | 1.859(2) | N(2)-Mn-O(1) | 109.1(2) |
| Mn-O(3)a | 2.313(7) | N(3)-Mn-O(2) | 111.9(9) |
| Mn-N(1) | 2.375(2) | N(1)-Mn-O(3)a | 163.1(2) |
| Mn-N(2) | 2.095(2) | N(1)-Mn-N(3) | 84.5(1) |
| Mn-N(3) | 2.091(2) | N(1)-Mn-N(2) | 84.6(9) |
O(3) refers to the O atom of the THF ligand
