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. Author manuscript; available in PMC: 2015 Feb 1.
Published in final edited form as: Chem Sci. 2014 Feb;5(2):545–550. doi: 10.1039/C3SC53014K

Scheme 6.

Scheme 6

Ring size effects. Competition of intramolecular silyl ether trapping vs. bimolecular dihydrogen transfer from cyclooctane (the external clock reaction).