Table 1.
E1/2(A/A+) | E1/2(A+/A2+) | E1/2(A/A−) | E1/2(A−/A2−) | D•106 | cΔGann | dΔHann | |
---|---|---|---|---|---|---|---|
bBB2 | 1.11 V | 1.15 V | −1.15 V | −1.22 V | 4.0 cm2/s | 2.33 eV | 2.23 eV |
BB3 | 1.14 V | 1.19 V | −1.17 V | −1.24 V | 4.0 cm2/s | 2.31 eV | 2.21 eV |
BB4 | 1.12 V | 1.17 V | −1.18 V | −1.24 V | 4.0 cm2/s | 2.30 eV | 2.20 eV |
E1/2 values were obtained by fitting the experimental results to digital simulations and are reported versus SCE.
Data for BB2 is reproduced from reference 46.
ΔGann = E1/2 (A/A+) − E1/2 (A/A−).
ΔHann = ΔGann − 0.1 eV.