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. Author manuscript; available in PMC: 2014 Nov 20.
Published in final edited form as: J Am Chem Soc. 2013 Aug 27;135(36):13558–13566. doi: 10.1021/ja406731f

Table 1.

aRedox potentials recorded for BB2BB4 in CH2Cl2.

E1/2(A/A+) E1/2(A+/A2+) E1/2(A/A) E1/2(A/A2−) D•106 cΔGann dΔHann
bBB2 1.11 V 1.15 V −1.15 V −1.22 V 4.0 cm2/s 2.33 eV 2.23 eV
BB3 1.14 V 1.19 V −1.17 V −1.24 V 4.0 cm2/s 2.31 eV 2.21 eV
BB4 1.12 V 1.17 V −1.18 V −1.24 V 4.0 cm2/s 2.30 eV 2.20 eV
a

E1/2 values were obtained by fitting the experimental results to digital simulations and are reported versus SCE.

b

Data for BB2 is reproduced from reference 46.

c

ΔGann = E1/2 (A/A+) − E1/2 (A/A).

d

ΔHann = ΔGann − 0.1 eV.