Table 1. Selected Structural Parameters of Complex 3 Obtained from X-ray Single-Crystal Diffraction Studies (Bond Lengths in Å and Angles in deg).
| Ti(1)–O(1) | 1.962(10) | Ti(1)–O(3) | 1.957(10) |
| O(1)–C(2) | 1.302(17) | O(3)–C(4) | 1.310(17) |
| O(2)–C(2) | 1.169(17) | O(4)–C(4) | 1.188(17) |
| C(2)–C(1) | 1.56(2) | C(4)–C(3) | 1.51(2) |
| Au(2)–P(2) | 2.226(4) | Au(1)–P(1) | 2.222(4) |
| Au(2)–Cl(2) | 2.279(4) | Au(1)–Cl(1) | 2.287(4) |
| Ti(1)–O(1) | 1.962(10) | Ti(1)–O(3) | 1.957(10) |
| O(1)–C(2) | 1.302(17) | O(3)–C(4) | 1.310(17) |
| O(2)–C(2) | 1.169(17) | O(4)–C(4) | 1.188(17) |
| C(2)–C(1) | 1.56(2) | C(4)–C(3) | 1.51(2) |
| Au(2)–P(2) | 2.226(4) | Au(1)–P(1) | 2.222(4) |
| Au(2)–Cl(2) | 2.279(4) | Au(1)–Cl(1) | 2.287(4) |
| average Ti(1)–C(21–25) | 2.381(2) | average C–C in Cp ring C(21)–C(25) | 1.386(3) |
| average Ti(1)–C(11–15) | 2.385(2) | average C–C in Cp ring C(11)–C(15) | 1.392(3) |
| distance Ti–Z (centroid of Cp) | 2.069 | ||
| Ti(1)–O(3)–C(4) | 141.0(9) | C23–Ti1–C12 | 171.9(7) |
| O(1)–Ti(1)–O(3) | 95.8(4) | O(3)–C(4)–O(4) | 123.0(13) |
| Ti(1)–O(1)–C(2) | 137.2(9) | O(4)–C(4)–C(3) | 122.6(14) |
| C15–Ti1–C21 | 100.9(9) | C(3)–C(4)–P(1) | 111.5(11) |
| O(1)–C(2)–O(2) | 126.5(15) | P(2)–Au(2)–Cl(2) | 173.71(19) |
| O(2)–C(2)–C(1) | 122.1(14) | P(1)–Au(1)–Cl(1) | 173.15(17) |
| C(1)–C(2)–P(2) | 112.8(11) |