Table 2.
Experimental results at different times for the precipitation of As-S mineral treatments at different pH (6.1, 6.45 and 7.1)
| Experiment | texp (d) | pHt | [TotAs]t (mM) | [SO42−]t (mM) | [H2S]t (mM) | Sloss/ASloss‡ |
|---|---|---|---|---|---|---|
| pH = 6.1 | 0 | 6.17 | 0.55±0.01 | 0.81±0.03 | 0.00±0.00 | -- |
| 6 | 5.93 | 0.05±0.02 | 0.12±0.01 | 0.01±0.00 | 1.34 | |
| 9 | 5.97 | 0.00±0.00 | 0.07±0.01 | 0.02±0.01 | 1.32 | |
| 12 | 5.90 | 0.00±0.00 | 0.09±0.01 | 0.03±0.01 | 1.25 | |
| 35 | 5.96 | 0.00±0.00 | 0.05±0.00 | 0.05±0.00 | 1.29 | |
|
| ||||||
| pH = 6.45 | 0 | 6.44 | 0.51±0.00 | 0.78±0.02 | 0.00±0.00 | -- |
| 6 | 6.49 | 0.25±0.03 | 0.35±0.02 | 0.05±0.01 | 1.47 | |
| 9 | 6.49 | 0.10±0.00 | 0.20±0.02 | 0.04±0.01 | 1.31 | |
| 12 | 6.47 | 0.07±0.02 | 0.17±0.04 | 0.04±0.01 | 1.31 | |
| 34 | 6.49 | 0.03±0.00 | 0.14±0.01 | 0.03±0.00 | 1.27 | |
|
| ||||||
| pH = 7.1 | 0 | 7.13 | 0.51±0.01 | 1.09±0.05 | 0.00±0.00 | -- |
| 6 | 7.15 | 0.39±0.01 | 0.87±0.05 | 0.08±0.01 | 1.27 | |
| 9 | 7.15 | 0.27±0.03 | 0.57±0.01 | 0.11±0.00 | 1.80 | |
| 12 | 7.19 | 0.24±0.00 | 0.38±0.03 | 0.26±0.02 | 1.72 | |
| 33 | 7.15 | 0.12±0.00 | 0.38±0.00 | 0.25±0.04 | 1.19 | |
S and As losses are defined as the difference between the total initial concentration and the concentration at time t:
Sloss = (SO42− + H2S)0 − (SO42− + H2S)t
Asloss = (TotAs)0 − (TotAs)t