Table 4. Regression parameters of isotherms for expressing adsorption of solution NH4 +-N to W-BC, C-BC and P-BC at different pyrolytic temperatures.
Biochars | Temp. (°C) | Freundlich model | Langmuir model | ||||
n | KF (L mg−1) | R2 | Qm (mg g−1) | KL (L mg−1) | R2 | ||
W-BC | 400 | 1.5375 | 0.0954 | 0.9612 | 7.3314 | 0.0042 | 0.7709 |
500 | 1.6717 | 0.0872 | 0.9398 | 4.6838 | 0.0050 | 0.8180 | |
600 | 1.7253 | 0.0789 | 0.9716 | 3.1636 | 0.0070 | 0.9191 | |
700 | 1.6949 | 0.0605 | 0.9437 | 2.6448 | 0.0065 | 0.8827 | |
C-BC | 400 | 1.5387 | 0.2778 | 0.9730 | 15.4560 | 0.0069 | 0.9117 |
500 | 1.8212 | 0.3246 | 0.9540 | 12.0482 | 0.0065 | 0.7892 | |
600 | 2.1110 | 0.4188 | 0.9414 | 8.6201 | 0.0099 | 0.8291 | |
700 | 2.1711 | 0.3964 | 0.9611 | 7.1685 | 0.0114 | 0.8989 | |
P-BC | 400 | 1.6981 | 0.2019 | 0.9544 | 10.5153 | 0.0050 | 0.7561 |
500 | 1.6139 | 0.1226 | 0.9048 | 9.9206 | 0.0032 | 0.4877 | |
600 | 1.4440 | 0.0604 | 0.9255 | 7.7761 | 0.0026 | 0.4132 | |
700 | 1.4821 | 0.0486 | 0.9681 | 4.01445 | 0.0044 | 0.7876 |