Table 3. Experimental details.
| Crystal data | |
| Chemical formula | [Mn(C48H36N4)(N)] |
| M r | 737.76 |
| Crystal system, space group | Monoclinic, P21/c |
| Temperature (K) | 100 |
| a, b, c (Å) | 14.2619 (10), 8.6200 (11), 15.4685 (18) |
| β (°) | 94.188 (7) |
| V (Å3) | 1896.6 (4) |
| Z | 2 |
| Radiation type | Cu Kα |
| μ (mm−1) | 3.14 |
| Crystal size (mm) | 0.17 × 0.11 × 0.03 |
| Data collection | |
| Diffractometer | Bruker SMART APEX2 area detector |
| Absorption correction | Multi-scan (SADABS; Bruker, 2012 ▶) |
| T min, T max | 0.529, 0.662 |
| No. of measured, independent and observed [I > 2σ(I)] reflections | 30677, 3602, 3184 |
| R int | 0.050 |
| (sin θ/λ)max (Å−1) | 0.610 |
| Refinement | |
| R[F 2 > 2σ(F 2)], wR(F 2), S | 0.051, 0.131, 1.03 |
| No. of reflections | 3602 |
| No. of parameters | 255 |
| H-atom treatment | H-atom parameters constrained |
| Δρmax, Δρmin (e Å−3) | 0.33, −0.38 |