Table 3.
Chemical structures, spectral shifts, and nitration chemistry of L-tryptophan derivatives with modified side chains.
| Substratea | Structure | Spectral Shift | Nitrationb |
|---|---|---|---|
| 6 |
|
Type I | ++ |
| 7 |
|
Type I | + |
| 8 |
|
Type I | ++ |
| 9 |
|
Type I | ++ |
| 10 |
|
Type I | ++ |
| 11 |
|
Type I | ++ |
| 12 |
|
Type I | ND |
| 13 |
|
Type I | ND |
Reaction conditions can be found in the experimental section. Differential UV-visible spectra can be found in Figure S14 and LC-MS chromatograms for nitrated substrates can be found in Figures S4–S9.
Abbreviations: not detected (ND).