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. Author manuscript; available in PMC: 2015 Oct 13.
Published in final edited form as: Chembiochem. 2014 Sep 2;15(15):2259–2267. doi: 10.1002/cbic.201402241

Table 3.

Chemical structures, spectral shifts, and nitration chemistry of L-tryptophan derivatives with modified side chains.

Substratea Structure Spectral Shift Nitrationb
6 graphic file with name nihms637153t6.jpg Type I ++
7 graphic file with name nihms637153t7.jpg Type I +
8 graphic file with name nihms637153t8.jpg Type I ++
9 graphic file with name nihms637153t9.jpg Type I ++
10 graphic file with name nihms637153t10.jpg Type I ++
11 graphic file with name nihms637153t11.jpg Type I ++
12 graphic file with name nihms637153t12.jpg Type I ND
13 graphic file with name nihms637153t13.jpg Type I ND
a

Reaction conditions can be found in the experimental section. Differential UV-visible spectra can be found in Figure S14 and LC-MS chromatograms for nitrated substrates can be found in Figures S4–S9.

b

Abbreviations: not detected (ND).