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. 2014 Dec 9;9(12):e114858. doi: 10.1371/journal.pone.0114858

Table 1. EXAFS parameters for Dy and Lu species adsorbed on salmon milt and reference materials (CN, coordination number; R, interatomic distance; ΔE0, threshold E0 shift; σ, Debye-Waller factor; least squares precisions are given to each value).

Sample k range (Å−1) Shell CNa R (Å)a ΔE0 (eV) σ2 (x103 Å2)a , b Residual (%)
Dy on CP 2.85–8.85 Dy-O 10.2±1.1 2.329±0.020 4.8±2.1 12.1±0.2 1.6
Dy-P 1.1±0.1 3.759±0.111 12.1±0.9
Dy on CMC 2.95–10.75 Dy-O 10.9±1.0 2.383±0.020 3.2±2.5 12.1±0.2 0.9
Dy-C 2.7±0.1 3.401±0.19 5.3±0.9
Dy on Ln resin 2.80–10.35 Dy-O 9.6±2.1 2.249±0.016 3.9±2.0 7.6±0.8 1.4
Dy-P 7.2±0.1 3.762±0.104 13.7*
Dy on DNA-filter hybrid, pH 3 2.66–9.38 Dy-O 11.9±2.8 2.343±0.020 2.7±2.1 12.1 0.8
Dy-P 1.2±0.2 3.742±0.027 12.1*
Dy on salmon milt, pH 3 2.75–9.45 Dy-O 10.5±1.1 2.308±0.019 2.2±2.0 11.0 1.0
Dy-P 2.1±0.1 3.795±0.027 6.7±0.9
Lu on CP 2.75–10.2 Lu-O 9.8±2.3 2.284±0.019 6.8±2.1 12.1±0.8 3.3
Lu-P 2.3±0.1 3.812±0.050 12.1*
Lu on CMC 2.80–10.35 Lu-O 10.1±2.3 2.298±0.019 6.3±2.1 10.8±0.8 1.3
Lu-C 3.6±0.1 3.328±0.050 4.9*
Lu on Ln resin 2.80–10.35 Lu-O 8.4±1.7 2.184±0.014 6.4±2.1 5.8±0.8 1.4
Lu-P 5.3±0.3 3.734±0.025 9.6±0.8
Lu on DNA-filter hybrid, pH 3 2.80–10.05 Lu-O 10.5±2.1 2.270±0.017 6.0±2.0 12.3±0.6 1.1
Lu-P 1.9±0.1 3.786±0.195 10.0±0.6
Lu on salmon milt, pH 3 2.90–10.40 Lu-O 8.2±1.7 2.203±0.015 6.7±2.1 6.7±0.8 1.1
Lu-P 3.5±0.1 3.773±0.112 4.1
a

Accuracy in the fitted parameters were estimated to be generally ±0.02 Å for R, ±20% for CN, and 20% for σ. [2], [31].

b

The numbers with * were fixed during the fitting of EXAFS spectra.