Table 2.

Substrate Scope for the Rh(II)-Catalyzed Reaction of Pyridotriazoles with Anilines and Aliphatic Amines.[^a,^b]

Entry	Product	Yield, %	Entry	Product	Yield, %
1		88	7		71
2		63	8		90
3		80	9		47
4		86	10		91[c]
5		72	11		87
6		76	12		82

^[a]Conditions: triazole 1 (0.20 mmol), N–H compounds 2 (1.5 equiv.), and Rh₂(esp)₂ (3.0 mol %) were heated in 2 ml of dry DCE at 120 °C until completion.

^[b]Isolated yields.

^[c]1.0 mol % of Rh₂(esp)₂.