Table 1.
Empirical coefficients obtained from the Langmuir model fitting and Kd coefficients estimated at Ce = 1.2 mmol·L−1 for the different ILs studied.
IL | [Na2SO4] (mol·kg−1) | qmax (mmol·g−1) | B (L·mmol−1) | R2 | Kd (L·kg−1) |
---|---|---|---|---|---|
|C4C1im|CI | No salt | 0.26 | 0.64 | 0.900 | 95 |
0.28 | 0.47 | 4.52 | 0.999 | 332 | |
0.70 | 0.54 | 3.02 | 0.997 | 353 | |
1.06 | 0.58 | 5.76 | 0.997 | 422 | |
1.41 | 0.74 | 3.54 | 0.961 | 498 | |
1.76 | 0.78 | 3.31 | 0.993 | 522 | |
| |||||
|C4C1im||CH3SO3| | No salt | 0.13 | 3.94 | 0.973 | 92 |
0.28 | 0.72 | 0.13 | 0.924 | 80 | |
0.70 | 0.34 | 7.54 | 0.939 | 254 | |
1.06 | 0.60 | 2.94 | 0.969 | 388 | |
1.41 | 0.45 | 78.04 | 0.977 | 374 | |
1.76 | 0.53 | 39.79 | 0.899 | 433 | |
| |||||
|C4C1im||CF3SO3| | No salt | 0.58 | 2.56 | 0.990 | 367 |
0.28 | 0.67 | 1.12 | 0.988 | 318 | |
0.70 | 0.57 | 3.52 | 0.997 | 385 | |
1.06 | 0.81 | 2.96 | 0.999 | 525 | |
1.41 | 0.93 | 2.10 | 0.995 | 556 | |
1.76 | 1.02 | 3.17 | 0.978 | 670 | |
| |||||
|C4C1im||NTf2| | No salt | 1.04 | 8.71 | 0.992 | 794 |
0.28 | 0.93 | 5.91 | 0.981 | 680 | |
0.70 | 0.99 | 5.73 | 0.999 | 719 | |
1.06 | 1.04 | 4.57 | 0.933 | 734 | |
1.41 | 1.02 | 16.99 | 0.964 | 809 | |
1.76 | 1.13 | 20.86 | 0.988 | 908 | |
| |||||
|C4C1py||NTf2| | No salt | 1.10 | 75.71 | 0.995 | 906 |
0.28 | 1.20 | 8.41 | 0.997 | 909 | |
0.70 | 1.47 | 5.69 | 0.997 | 1068 | |
1.06 | 1.15 | 23.72 | 0.991 | 929 | |
1.41 | 1.32 | 61.70 | 0.989 | 1088 | |
1.76 | 1.41 | 406.48 | 0.458 | 1173 |