TABLE 4.
13C NMR chemical shifts of the hopanoid residue (34-carboxyl-bacteriohopane-32,33-diol) of B. japonicum lipid A
Carbon atom | δ | |
---|---|---|
ppm | ||
1 | -CH2 | 40.66 |
2 | -CH2 | 19.02 |
3 | -CH2 | 42.40 |
4 | -C | 33.50 |
5 | -CH | 56.62 |
6 | -CH2 | 19.01 |
7 | -CH2 | 33.42 |
8 | -C | 42.00 |
9 | -CH | 50.00 |
10 | -C | 37.78 |
11 | -CH2 | 20.51 |
12 | -CH2 | 24.28 |
13 | -CH | 50.10 |
14 | -C | 41.90 |
15 | -CH2 | 33.98 |
16 | -CH2 | 23.27 |
17 | -CH | 55.06 |
18 | -C | 44.73 |
19 | -CH2 | 41.99 |
20 | -CH2 | 28.06 |
21 | -CH | 46.45 |
22 | -CH | 37.22 |
23 | -CH3 | 33.61 |
24 | -CH3 | 21.73 |
25 | -CH3 | 16.16 |
26 | -CH3 | 16.86 |
27 | -CH3 | 16.70 |
28 | -CH3 | 16.28 |
29 | -CH3 | 20.58 |
30 | -CH2 | 32.51 |
31 | -CH2 | 28.52 |
32 | -CH-OH | 73.99 |
33 | -CH-OH | 74.94 |
34 | -COOR*a | 172.73 |
a R*, lipid A (-(ω-1)-OH-group).