Table 3.
Retention index (RI), aroma properties and molecular origin of volatile compounds arising from oxidation of n-3 fatty acids (FA). Units of Equivalents (rightmost column) are percent of compound originating from the terminal end.
| Compound | RI1 | Odour descriptor | Equivalents of terminal end in fragment (%) |
|---|---|---|---|
| Acetaldehyde | 812 | Apple skin, fruity, green leaves, sweet, sweet burninga,b | 20 |
| Propanal | 833 | Sharp-irritatingc | 97 |
| 2-Propanone | 842 | Pungent, irritatingb | 0 |
| 2-Propenal | 857 | Irritatingb | 0 |
| Butanal | 873 | Burnt, irritating, green, penetrating pungent, varnishb | 65 |
| 2-Butanone | 890 | - | 45 |
| 2-Ethylfuran | 940 | Flowerc | 100 |
| 2-Pentanone | 968 | Acetone, sweet fruity ketoneb | 96 |
| 1-Penten-3-one | 1018 | Pungent, rancid green, glue, sharp fishyc | 100 |
| (E)-2-Butenal | 1039 | Old cheesec | 100 |
| 2,3-Pentanedione | 1059 | Butter-likea | 100 |
| Hexanal | 1080 | Pungent, green, fresh grass, fattya,c | 48 |
| (E)-3-Penten-2-one | 1125 | - | ? |
| (E)-2-Pentenal | 1128 | Pungent, glue, green, grassy, applec | 100 |
| 1-Penten-3-ol | 1156 | Sweetc | 100 |
| 3-Hexen-2-one | 1214 | - | 91 |
| 1 -Hydroxy-2-propanone | 1300 | - | 0 |
| (E)-2-Penten-1-ol | 1308 | Greenc | 100 |
| 2-Hydroxy-3-pentanone | 1355 | - | 100 |
| 1 -Hydroxy-2-butanone | 1373 | - | 100 |
| Acetic acid | 1450 | Vinegaryd | 2 |
| (E,E)-2,4-Heptadienal | 1492 | Nasty, green, fatty, fatty-oily, rancid hazelnutsa,c | ? |
| Propanoic acid | 1538 | Goaty, vinegar, cooked, potato-liked,e | 100 |
| 5-Methyl-2(5H)-Furanone | 1684 | Caramel, fruity, phenolicse | ? |
| 5-Ethyl-2(5H)-Furanone | 1765 | - | 100 |
- Data not found. ? No conclusive data were obtained from the present study.
Retention index on DB-FFAP.
The LRI and Odour Database.