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. Author manuscript; available in PMC: 2016 May 1.
Published in final edited form as: Food Chem. 2014 Nov 8;0:310–318. doi: 10.1016/j.foodchem.2014.11.015

Table 3.

Retention index (RI), aroma properties and molecular origin of volatile compounds arising from oxidation of n-3 fatty acids (FA). Units of Equivalents (rightmost column) are percent of compound originating from the terminal end.

Compound RI1 Odour descriptor Equivalents of terminal end in fragment (%)

Acetaldehyde 812 Apple skin, fruity, green leaves, sweet, sweet burninga,b 20
Propanal 833 Sharp-irritatingc 97
2-Propanone 842 Pungent, irritatingb 0
2-Propenal 857 Irritatingb 0
Butanal 873 Burnt, irritating, green, penetrating pungent, varnishb 65
2-Butanone 890 - 45
2-Ethylfuran 940 Flowerc 100
2-Pentanone 968 Acetone, sweet fruity ketoneb 96
1-Penten-3-one 1018 Pungent, rancid green, glue, sharp fishyc 100
(E)-2-Butenal 1039 Old cheesec 100
2,3-Pentanedione 1059 Butter-likea 100
Hexanal 1080 Pungent, green, fresh grass, fattya,c 48
(E)-3-Penten-2-one 1125 - ?
(E)-2-Pentenal 1128 Pungent, glue, green, grassy, applec 100
1-Penten-3-ol 1156 Sweetc 100
3-Hexen-2-one 1214 - 91
1 -Hydroxy-2-propanone 1300 - 0
(E)-2-Penten-1-ol 1308 Greenc 100
2-Hydroxy-3-pentanone 1355 - 100
1 -Hydroxy-2-butanone 1373 - 100
Acetic acid 1450 Vinegaryd 2
(E,E)-2,4-Heptadienal 1492 Nasty, green, fatty, fatty-oily, rancid hazelnutsa,c ?
Propanoic acid 1538 Goaty, vinegar, cooked, potato-liked,e 100
5-Methyl-2(5H)-Furanone 1684 Caramel, fruity, phenolicse ?
5-Ethyl-2(5H)-Furanone 1765 - 100

- Data not found. ? No conclusive data were obtained from the present study.

1

Retention index on DB-FFAP.

b

The LRI and Odour Database.