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. 2014 Nov 7;136(49):17273–17283. doi: 10.1021/ja5098308

Figure 3.

Figure 3

Free energy changes of [Rh(CO)2Cl]2-catalyzed (5 + 2) cycloaddition and allene dimerization pathways with dimethyl-substituted allene-yne 10. Gibbs free energies (298 K) with respect to 15 are shown in kcal/mol.