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. 2014 Nov 11;136(48):16720–16723. doi: 10.1021/ja5094309

Table 1. Ligand-Controlled, Silver-Catalyzed C–H Amination.

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a

C–H insertion: 10 mol % AgOTf, 10–30 mol % ligand, 3.5 equiv of PhIO, 4 A MS, 0.05 M CH2Cl2.

b

Rh cat.: 2 mol %, 1.1 equiv of PhI(OAc)2, 2.3 equiv of MgO, CH2Cl2.

c

See Supporting Information for the conditions for entries 5–7.

d

Total NMR yield. Average of 2 runs, mesitylene internal standard.d