Scheme 3. Scope of this Methodology: Ketone (5–11), Secondary Alcohol (12–14), TMS (15), F (16), and Azide (17) Functionalized P3HTs.

The conversion determined by ¹⁹F NMR with trifluorotoluene as an internal standard in NMR solvent. EA showed 46% conversion (See Supporting Information).

The conversion is slightly overestimated due to overlapped peaks in the aryl region of the ¹H NMR spectra with CdCl3.

The conversion cannot be calculated with a single value due to the overlapped peaks of α-CH₂ of hexyl chain with Ar-Me.

Slightly different reaction contions are employed. Please see below and Supporting Information for detailed conditions.

The conversion was not available due to the insolubility of the product.