An analytic
model which captures the relevant physics. (A) The simplest model
is an infinite cylinder with external and internal axially directed
electric fields in opposite directions. This drives electroosmotic
flows in opposite directions. The electric field ratio α was
set to 0.1 in all of the analytic calculations. (B) The flow profiles
inside and outside a cylinder of radius a and wall
thickness a, at two different salt concentrations
κ = 0.001 (solid lines) and κ = 1.0 (dashed lines), where
κ is measured in units of a–1. The maximum velocity vmax in each case
was calculated at r = 0 for the inner flow and at r = λD for the outer flow. In the high
salt case vmax,in > vmax,out, whereas in the low salt case it is the other
way around. (C) The normalized momentum flux generated by the inner
(solid line) and outer (dashed line) walls, as a function of salt
concentration for an infinite cylinder. As salt is reduced, the inner
flux saturates, while the outer flux carries on growing. (D) The normalized
net momentum flux exhibits the same qualitative flow reversal behavior
as observed in the experiments and simulations.