Table 3. Selected Hydrogen Bonding Parameters (Å, deg) for the Halide Complexes of La.
D–H···A | D···A | H···A | ∠D–H···A |
---|---|---|---|
1 | |||
N1–H1···Cl1 | 3.0674(18) | 2.14 | 178.1 |
N2–H22···Cl1 | 3.126(2) | 2.25 | 159.5 |
N3–H32N···Cl1 | 3.146(2) | 2.23 | 170.6 |
2 | |||
N2–H21N···Br1 | 3.3398(12) | 2.48(2) | 168.0(19) |
N3–H31N···Br1 | 3.3622(12) | 2.52(2) | 167.2(19) |
3 | |||
N(4)–H(4A)···I(2) | 3.827(5) | 3.22(6) | 129(4)) |
N(13)–H(13B)···I(2)i | 2.76(5) | 3.573(5) | 159(5) |
N(4)–H(4B)···O(1S) | 2.13(6) | 2.935(6) | 157(5) |
N(13)–H(13A)···O(1S)i | 2.10(6) | 2.948(6) | 178(5) |
O(1S) −H(1S) ···I(1) | 2.87(6) | 3.539(4) | 148(6) |
(i) Symmetry code: 1 – x + 1, −y + 1, −z.