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. 2014 Sep 23;18(11):1503–1508. doi: 10.1021/op5002676

Table 1. Loss of catalyst activity during oxidation of benzyl alcohola.

entry catalyst source yieldb (%)
1 first use >98
2 second use 17
3 after NaOH regenerationc >98
a

0.15 M benzyl alcohol, 3.3 mol % Ru as Ru(OH)x/Al2O3, 80 °C, 1 h, 1 bar O2, 1.5 mL toluene.

b

GC yield using tetradecane as an internal standard.

c

Used catalyst was stirred in 0.1 M NaOH for 16 h, then washed with water and dried in vacuum prior to reuse.