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. Author manuscript; available in PMC: 2015 Jan 20.
Published in final edited form as: Chem Rev. 2014 Mar 24;114(7):3495–3578. doi: 10.1021/cr400458x

Figure 11.

Figure 11

(A) Calculated electron transfer pathway from the disulfide bond to the copper site in Az mutants. Residues involved in electron transfer are in red. (B) Logarithm of the electron transfer rate constants as a function of the driving force of the reaction (dots) and the theoretically calculated bell-shaped curve. Mutants: 1, Phe114Pro/Met121Gln; 2, Phe114Pro; 3, Asn47Ser/Phe114Asn; 4, Asn47Ser/Met121Leu; 5, Phe114Asn/ Met121Leu; 6, Asn47Ser/Phe114Asn/Met121Leu. Reproduced with permission from ref 393. Copyright 2013 National Academy of Sciences.