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. Author manuscript; available in PMC: 2015 Jan 20.
Published in final edited form as: Chem Rev. 2014 Mar 24;114(7):3495–3578. doi: 10.1021/cr400458x

Figure 47.

Figure 47

(A) A model of Cu(TRIL23H)32+/+ based on the crystal structure of Hg(II)SZn(II)N(CSL19PenL23H)3+ (PDB code: 3PBJ213). Overlay of the Zn(II)(His)3(OH2/OH−) site in Hg(II)SZn-(II)N(CSL19PenL23H)3+ (protein ligands: dark blue; zinc: dark blue sphere; zinc-bound water: red sphere) and the T1Cu center in CuNiR from R. sphaeroides (PDB code: 2DY2.958 Protein ligands: light green and teal; copper: cyan sphere; copper-bound water: light pink sphere). (B) Top view. (C) Side view. Adapted with permission from 214. Copyright 2012 National Academy of Sciences.