Table 2.
JFS sample | Temperature (°C) | ΔT | ΔH | FT-IR ratio | Swelling power at T (°C) | Solubility at T (°C) | ||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
T o | T p | T c | (J/g) | RT | 50 | 60 | 70 | 80 | 90 | RT | 50 | 60 | 70 | 80 | 90 | |||
Native | 82.58 ± 0.24 | 84.24 ± 0.37 | 88.63 ± 0.12 | 6.05 ± 0.31 | 11.25 ± 0.06 | 0.80 ± 0.01 | 1.1 | 1.3 | 2.3 | 2.5 | 6.8 | 7.7 | 0.4 | 1.3 | 2.4 | 2.8 | 7.2 | 9.5 |
| ||||||||||||||||||
80°C | ||||||||||||||||||
10% MC | 82.28 ± 0.94 | 84.41 ± 0.54 | 88.75 ± 0.07 | 6.47 ± 0.37 | 10.14 ± 0.06 | 0.82 ± 0.03 | 1.1 | 1.3 | 2.1 | 2.9 | 5.3 | 7.0 | 0.5 | 1.5 | 2.2 | 2.9 | 7.2 | 9.3 |
20% MC | 82.52 ± 0.31 | 85.38 ± 0.24 | 88.25 ± 0.21 | 5.73 ± 0.10 | 7.44 ± 0.26 | 0.85 ± 0.02 | 1.0 | 1.4 | 2.3 | 2.9 | 5.0 | 6.7 | 0.7 | 1.5 | 2.3 | 3.1 | 7.1 | 9.2 |
25% MC | 86.10 ± 0.12 | 88.79 ± 0.39 | 91.65 ± 1.06 | 5.55 ± 0.94 | 7.27 ± 0.73 | 0.84 ± 0.02 | 1.1 | 1.5 | 2.5 | 2.8 | 3.2 | 5.7 | 0.7 | 1.7 | 2.3 | 3.2 | 7.3 | 9.1 |
30% MC | 89.22 ± 0.27 | 91.03 ± 0.13 | 93.25 ± 0.21 | 4.03 ± 0.06 | 4.49 ± 0.23 | 0.83 ± 0.03 | 1.1 | 1.2 | 2.4 | 2.7 | 4.3 | 5.5 | 0.6 | 1.6 | 2.5 | 3.0 | 7.2 | 9.2 |
35% MC | 89.32 ± 0.14 | 91.14 ± 0.16 | 93.40 ± 0.71 | 4.08 ± 0.85 | 5.04 ± 0.36 | 0.85 ± 0.04 | 1.2 | 1.2 | 2.6 | 2.6 | 5.0 | 6.1 | 0.5 | 1.7 | 2.6 | 3.1 | 7.3 | 9.6 |
| ||||||||||||||||||
90°C | ||||||||||||||||||
10% MC | 82.14 ± 1.20 | 85.01 ± 0.63 | 88.05 ± 0.92 | 5.91 ± 0.28 | 9.20 ± 0.95 | 0.78 ± 0.06 | 1.0 | 1.2 | 2.3 | 3.1 | 5.9 | 7.3 | 0.4 | 1.4 | 2.3 | 2.9 | 6.8 | 9.1 |
20% MC | 85.71 ± 0.09 | 88.20 ± 0.40 | 91.90 ± 1.41 | 6.19 ± 1.51 | 8.12 ± 1.10 | 0.84 ± 0.04 | 1.1 | 1.5 | 2.7 | 3.3 | 5.5 | 6.9 | 0.4 | 1.5 | 2.4 | 3.2 | 7.0 | 9.3 |
25% MC | 91.62 ± 0.20 | 93.49 ± 0.55 | 96.20 ± 1.13 | 4.58 ± 0.93 | 7.41 ± 1.12 | 0.77 ± 0.05 | 1.1 | 1.4 | 2.6 | 2.9 | 5.6 | 6.7 | 0.3 | 1.6 | 2.4 | 3.1 | 6.8 | 9.2 |
30% MC | 90.57 ± 0.23 | 92.53 ± 0.16 | 95.00 ± 0.57 | 4.43 ± 0.80 | 5.11 ± 0.99 | 0.78 ± 0.06 | 1.0 | 1.3 | 2.5 | 3.2 | 5.3 | 6.2 | 0.4 | 1.5 | 2.6 | 3.1 | 7.0 | 9.3 |
35% MC | 91.35 ± 0.48 | 93.57 ± 0.56 | 96.50 ± 1.56 | 5.15 ± 1.08 | 4.87 ± 1.37 | 0.75 ± 0.05 | 1.0 | 1.4 | 2.7 | 2.9 | 5.4 | 6.6 | 0.4 | 1.8 | 2.6 | 3.0 | 7.0 | 9.5 |
| ||||||||||||||||||
100°C | ||||||||||||||||||
10% MC | 81.68 ± 0.44 | 84.69 ± 0.45 | 89.00 ± 0.85 | 7.32 ± 0.41 | 10.75 ± 0.33 | 0.78 ± 0.03 | 1.1 | 1.3 | 2.2 | 3.1 | 5.6 | 6.5 | 0.5 | 1.2 | 2.3 | 3.0 | 6.6 | 8.9 |
20% MC | 85.37 ± 0.32 | 88.18 ± 0.51 | 91.75 ± 1.20 | 6.38 ± 0.88 | 8.93 ± 1.04 | 0.76 ± 0.03 | 1.1 | 1.2 | 2.3 | 3.2 | 5.2 | 5.8 | 0.4 | 1.1 | 2.3 | 2.9 | 5.7 | 8.2 |
25% MC | 89.13 ± 0.27 | 92.07 ± 0.03 | 95.25 ± 0.21 | 6.12 ± 0.06 | 5.80 ± 0.93 | 0.76 ± 0.05 | 1.0 | 1.2 | 2.5 | 2.9 | 4.8 | 5.4 | 0.5 | 1.1 | 2.4 | 2.8 | 5.0 | 7.5 |
30% MC | 92.12 ± 0.09 | 94.29 ± 0.05 | 97.60 ± 0.00 | 5.48 ± 0.09 | 4.38 ± 0.64 | 0.75 ± 0.03 | 1.0 | 1.1 | 2.2 | 2.8 | 4.0 | 5.3 | 0.5 | 1.3 | 2.3 | 2.7 | 4.7 | 7.2 |
35% MC | 93.26 ± 0.01 | 95.45 ± 0.07 | 98.05 ± 0.04 | 4.79 ± 0.22 | 1.80 ± 0.06 | 0.70 ± 0.05 | 1.1 | 1.1 | 2.2 | 2.5 | 3.3 | 4.6 | 0.4 | 1.1 | 2.2 | 2.6 | 4.4 | 6.9 |
| ||||||||||||||||||
110°C | ||||||||||||||||||
10% MC | 81.66 ± 0.38 | 84.50 ± 0.27 | 88.25 ± 0.21 | 6.59 ± 0.59 | 9.35 ± 1.33 | 0.81 ± 0.01 | 1.0 | 1.3 | 2.3 | 3.2 | 5.8 | 7.2 | 0.3 | 1.3 | 2.4 | 3.4 | 7.0 | 9.0 |
20% MC | 84.92 ± 0.90 | 87.34 ± 0.15 | 91.55 ± 0.21 | 6.63 ± 1.12 | 3.10 ± 1.36 | 0.84 ± 0.02 | 1.0 | 1.3 | 2.4 | 3.2 | 5.4 | 6.8 | 0.3 | 1.3 | 2.5 | 3.5 | 7.2 | 8.8 |
25% MC | 86.49 ± 1.25 | 90.95 ± 0.12 | 94.80 ± 0.85 | 8.31 ± 0.40 | 4.55 ± 0.84 | 0.77 ± 0.05 | 1.2 | 1.6 | 2.7 | 3.3 | 5.5 | 6.5 | 0.4 | 1.2 | 2.5 | 3.4 | 7.2 | 8.7 |
30% MC | 89.21 ± 0.67 | 91.92 ± 0.66 | 95.75 ± 0.92 | 6.54 ± 0.25 | 4.75 ± 1.20 | 0.76 ± 0.03 | 1.2 | 1.4 | 2.7 | 3.4 | 4.9 | 6.1 | 0.4 | 1.3 | 2.6 | 3.7 | 7.3 | 8.9 |
35% MC | 89.29 ± 0.17 | 92.31 ± 0.18 | 95.55 ± 0.21 | 6.26 ± 0.05 | 1.63 ± 0.07 | 0.78 ± 0.04 | 1.2 | 1.5 | 2.8 | 3.6 | 4.8 | 6.5 | 0.4 | 1.4 | 2.5 | 3.6 | 7.6 | 9.4 |
| ||||||||||||||||||
120°C | ||||||||||||||||||
10% MC | 81.75 ± 0.72 | 84.76 ± 0.73 | 89.05 ± 2.19 | 7.30 ± 1.47 | 9.29 ± 0.93 | 0.82 ± 0.02 | 1.1 | 1.2 | 2.2 | 3.2 | 5.7 | 7.0 | 0.5 | 1.6 | 2.2 | 3.3 | 7.4 | 9.2 |
20% MC | 86.05 ± 4.47 | 86.48 ± 0.21 | 90.65 ± 0.07 | 6.60 ± 0.54 | 4.14 ± 0.25 | 0.82 ± 0.03 | 1.1 | 1.3 | 2.4 | 3.3 | 5.9 | 6.8 | 0.4 | 1.6 | 2.3 | 3.4 | 7.3 | 9.3 |
25% MC | 87.33 ± 2.10 | 90.91 ± 0.14 | 93.90 ± 0.57 | 6.57 ± 0.66 | 3.88 ± 0.90 | 0.77 ± 0.05 | 1.3 | 1.4 | 2.5 | 2.9 | 5.5 | 6.6 | 0.5 | 1.8 | 2.3 | 3.6 | 7.5 | 9.6 |
30% MC | 86.92 ± 0.27 | 90.88 ± 0.96 | 95.80 ± 0.99 | 8.88 ± 1.26 | 3.18 ± 0.74 | 0.74 ± 0.04 | 1.3 | 1.5 | 2.6 | 3.1 | 5.5 | 6.9 | 0.5 | 1.9 | 2.5 | 3.5 | 7.4 | 9.4 |
35% MC | 88.27 ± 0.16 | 91.68 ± 0.19 | 94.75 ± 0.35 | 6.48 ± 0.19 | 2.28 ± 0.35 | 0.69 ± 0.03 | 1.2 | 1.5 | 2.6 | 3.4 | 5.8 | 7.2 | 0.5 | 1.6 | 2.6 | 3.3 | 7.5 | 9.5 |