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. Author manuscript; available in PMC: 2015 Nov 3.
Published in final edited form as: Chembiochem. 2014 Sep 18;15(16):2402–2410. doi: 10.1002/cbic.201402295

Table 2.

Correlation between exchange-broadening and chemical shifts in ShK.

Residue Φexa × 103 (s−2) δ15N ppm δ15NRCb ppm (Δδ15N)2 × 106 (s−2)
M21 27.5a 130.4 119.6b 17.0c
L25 22.4 111 121.8 17.0
H19 16.8 112.9 118.2 4.1
K18 14.5 115.4 120.4 3.6
T31 11.6 124.2 113.6 16.4
Y23 10.5 120.2 120.9 0.1
S10 9.3 113.9 116.3 0.8
C12 8.7 122.4 120.1 0.8
T13 8.4 110.2 113.6 1.7
K9 8.3 123.9 120.4 1.8
R24 6.4 117.2 120.5 1.6
a

From the global fit at 14.1 T

b

Based on BMRB chemical shift statistics, http://www.bmrb.wisc.edu

c

Calculated as (δ15N – δ15NRC)2 × (ωN)2 at 14.1 T