Table 1. Standard Gibbs free energies for the S-(+) and R-(−) carvones binding to the pOBP.
(kJ mol−1)
|
(kJ mol−1)
|
(kJ mol−1)
|
W (kJ mol−1) | |
|---|---|---|---|---|
| S-(+) | −(49.2±0.1) | −(36.00±0.05) | −(5.8±0.5) | −(7.2±0.5) |
| R-(−) | −(41±2) | −(33.0±0.1) | −(1.1±0.5) | −(7.9±2) |
| ΔG0+−ΔG0− | −(7±2) | −(3.0±0.2) | −(4.7±1) |
is estimated from the WGOFET binding curves of Fig. 5b; 
is the molar electrostatic energy evaluated from the WGOFET VT shift; 
is the binding free energy of the pOBP dissolved in solution; 
is the surface binding work.