Table 5. Perfluoroalkyl Derivatives of Higher Fullerenes.
| fullerene | characterized PFAFs | structural method | ref |
|---|---|---|---|
| C74-D3h(1) | C74(CF3)12 | X-ray, 19F NMR | (50,57) |
| C76-D2(1) | C76(CF3)6 | 19F NMR | (70) |
| C76(CF3)8, two isomers | 19F NMR | (70) | |
| C76(CF3)10, five isomers | 19F NMR | (70) | |
| C76(CF3)12 | 19F NMR | (70) | |
| C76(CF3)14 | X-ray | (90) | |
| C76(CF3)16, three isomers | X-ray | (90,165) | |
| C76(CF3)18, two isomers | X-ray | (90) | |
| C76-Td(2) | C76(CF3)12 | 19F NMR | (50) |
| C78-D3(1) | C78(CF3)10 | X-ray, 19F NMR | (70) |
| C78-C2v(2) | C78(CF3)10, two isomers | X-ray, 19F NMR | (70) |
| C78(C2F5)10 | X-ray | (78) | |
| C78-C2v(3) | C78(CF3)8 | 19F NMR | (70) |
| C78(CF3)12 | X-ray, 19F NMR | (70) | |
| C78-D3h(5) | C78(CF3)12 | X-ray, 19F NMR | (50,57) |
| C80-D2(2) | C80(CF3)12 | X-ray | (139c) |
| C80-C2v(5) | C80(CF3)12 | 19F NMR | (50) |
| C82-C2(3) | C82(CF3)12 | 19F NMR, X-ray | (50,96) |
| C82(CF3)16, two isomers | X-ray | (165) | |
| C82(CF3)18, two isomers | X-ray | (96) | |
| C82-C2(5) | C82(CF3)12 | 19F NMR | (50) |
| C84-D2d(4) | C84(CF3)12 | X-ray | (84b) |
| C84-D2(5) | C84(CF3)16 | X-ray | (166a) |
| C84-C2(11) | C84(CF3)12 | 19F NMR, X-ray | (69) |
| C84(C2F5)12 | X-ray | (83) | |
| C84-Cs(16) | C84(C2F5)12, two isomers | X-ray | (83,84b) |
| C84-C2v(18) | C84(C2F5)12 | X-ray | (83) |
| C84-D2(22) | C84(CF3)6 | X-ray | (167) |
| C84(CF3)12, two isomers | 19F NMR, X-ray | (70,107) | |
| C84(C2F5)12 | X-ray | (83) | |
| C84(CF3)14, two isomers | X-ray | (107) | |
| C84(CF3)16, four isomers | X-ray | (83,107) | |
| C84(CF3)20 | X-ray | (107) | |
| C84-D2d(23) | C84(CF3)4 | X-ray | (108) |
| C84(CF3)8 | X-ray | (108) | |
| C84(CF3)10 | X-ray | (108) | |
| C84(CF3)12 | X-ray | (108) | |
| C84(C2F5)12 | X-ray | (83) | |
| C84(CF3)14, two isomers | X-ray | (108) | |
| C84(CF3)16, two isomers | X-ray | (108) | |
| C84(CF3)18 | X-ray | (108) | |
| C86-C2(17) | C86(CF3)16, two isomers | X-ray | (81) |
| C86(CF3)18 | X-ray | (81) | |
| C88-C2(33) | C88(CF3)16 | X-ray | (139b) |
| C88(CF3)18 | X-ray | (86) | |
| C88(CF3)18 | X-ray | (139b) | |
| C90-C1(30) | C90(CF3)18 | X-ray | (168) |
| C90-C1(32) | C90(CF3)12 | 19F NMR | (70) |
| C90-Cs(35) | C90(CF3)14 | X-ray | (168) |
| C92-D2(82) | C90(CF3)16 | X-ray | (86) |
| C94-C2(61) | C94(CF3)20; two THJs | X-ray | (84a) |
| C96-C1(145) | C96(C2F5)12 | X-ray | (84a) |